The usual causes of that error are either incorrect GC Integration settings, or it can also happen if you receive any payments via GC that were not initiated from E-junkie purchase buttons.
Our required Google Checkout integration settings will have them attempt to inform our system of every payment you receive through their checkout process. If you are receiving any Google Checkout payments that were not initiated from E-junkie Cart or Buy Now buttons (e.g., if you use the "Send An Invoice" function in your Google Checkout account to request a payment manually), GC would still dutifully try to notify our system about those payments; however, our system would refuse to process an order that was not placed through our system to begin with, generating this error at GC's end that you can simply ignore.