That is not an E-junkie issue. PayPal payments can be pending if they are madeusing abnk account (echeck) in which case they take 4-5 days to clear OR they can be pending due to your PayPal account settings, in which case, once you accept the payment, PayPal will ask and store your pref.
In E-junkie Admin > Preferences, you can instruct E-junkie to process your pending payments are instant payments.